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Benzillic acid rearrangement:
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When 1,2-diketones ( α-diketones) on treatment with alcoholic KOH to give  alpha- hydroxy acid. This is intramolecular base catalyased reaction. This is called as pi molecular rearrangement with second order rate reaction. In this rearrangement migrating group migrates towards electron deficient carbon atom.In this rearrangement  Less eletron releasing  group migrates first.

Subject:
Chemistry
Material Type:
Lecture Notes
Author:
Subhash Junne
Date Added:
05/03/2020